Centre for Analytical and Environmental Chemistry, Department of Chemistry, Carleton University, 1125 Colonel By Drive, Ottawa, Ontario K1S 5B6, Canada, Department of Toxicology, Wageningen Agricultural University, Tuinlaan 5, 6703 HE Wageningen, The Netherlands, Wellington Laboratories Inc., 398 Laird Road, Guelph, Ontario, N1G 3X7 Canada, Research Institute of Toxicology, Utrecht University,…

In this study, we identified the main hydroxylated polychlorinated biphenyls (OH-PCBs) and other chlorinated phenolic compounds and we determined their relative concentrations in whole blood from 13 male and 17 female Inuit from northern Quebec, Canada, and from a pooled whole blood sample from southern Quebec. We also determined concentrations…

The enantiomer ratios (ERs) of α-HCH and chlordane related compounds (CHLs) were examined in the polar bear food chain (arctic cod−ringed seal−polar bear), using chiral gas chromatography−mass spectrometry (GC-MS). The cod showed near-racemic mixtures (ER = 1) for most of the compounds. In contrast, ERs in ringed seal and polar…

Four different commercially available cyclodextrin (CD) capillary gas chromatography (GC) columns were tested for the enantioselective separation of nine environmentally persistent atropisomeric 3- and 4-methylsulfonyl PCBs (MeSO2-CBs). The selected columns contained cyclodextrins with various cavity diameters (β- or γ-CD), which were methylated and/or tert-butyldimethylsilylated (TBDMS) in the 2,3,6-O-positions. The β-CD column…